2,2-Dimethyl-N-(2-methylphenylsulfonyl)propanamide
نویسندگان
چکیده
In the title compound, C(12)H(17)NO(3)S, the amide H atom is syn to the ortho-methyl group of the benzene ring and the C-S-N-C torsion angle is -65.39 (17)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds in which the acceptor O atom is bound to the S atom.
منابع مشابه
Bis{(E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(II)} bis((E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) acetonitrile disolvate
The reaction between copper(II) nitrate and (E)-N-(3-amino-2,2-dimethyl-prop-yl)-2-(hy-droxy-imino)-propanamide led to the formation of the dinuclear centrosymmetric copper(II) title complex, (C8H18N3O2)2[Cu2(C8H15N3O2)2(C8H17N3O2)2](C9H16N3O4)2·2CH3CN, in which an inversion center is located at the midpoint of the Cu2 unit in the center of the neutral [Cu2(C8H15N3O2)2(C8H17N3O2)2] complex frag...
متن کامل4-(3-Chloro-2,2-dimethylpropanamido)benzenesulfonamide
In the title compound, C11H15ClN2O3S, the 3-chloro-2,2-dimethyl-propanamide and sulfonamide substituents are arranged on opposite sides of the benzene ring plane. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional network.
متن کاملN-Ethyl-2,2-dimethyl-N-(3-methylphenyl)propanamide
In the title compound, C14H21NO, the conformation across the N-C(O) bond is syn-periplanar, the C-N-C-C torsion being -5.9 (5)°. The atoms of the ethyl group attached to the N atom are disordered over two sets of sites with occupancy ratios of 0.65 (2):0.35 (2) (CH2) and 0.689 (14):0.311 (14) (CH3)are linked by very weak C-H⋯O inter-actions forming C(8) chains along [001]. C-H⋯π inter-actions l...
متن کامل2,2-Dimethyl-N-(2-methylphenylsulfonyl)acetamide
The asymmetric unit of the title compound, C(11)H(15)NO(3)S, contains two independent mol-ecules in which the amide bonds show a trans conformation. The C-S-N-C torsion angles are -67.4 (2) and 63.8 (2)° in the two independent mol-ecules. In one of the mol-ecules, a methyl group is disordered over two sets of sites with a site-occupation factor of 0.661 (16) for the major occupany component. In...
متن کاملN-(2-Methylphenylsulfonyl)propanamide
In the title compound, C(10)H(13)NO(3)S, the conformations of the N-H and C=O bonds of the SO(2)-NH-CO-C segment are anti to each other, while the amide H atom is syn with respect to the ortho-methyl group in the benzene ring. The C-S-N-C torsion angle is -66.7 (2)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O(S) hydrogen bonds.
متن کامل